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Survey of the 2‐alkylbenzophenones 2 which can participate in the photochemical organocatalytic desymmetrization aldol process. Reactions performed on a 0.1 mmol scale using 3 equiv of 2. The d.r. value is inferred by 19F NMR analysis of the crude reaction mixture. Yields and enantiomeric excesses of the isolated products 3 are indicated below each entry (average of two runs).
