Table 3.
Effects of Moving the W/W Cap to Different Distances from the Turn.
| Spectroscopic diagnostics at 280K (corrected to χF = 1) |
||||||
|---|---|---|---|---|---|---|
| W/W position | Turn Type | Sequence | χF (300K) | Hε3 CSD | [θ]228 CD max. | |
| 1 | S±2 | 2:4 | KKLTVW-INGK-WITVSA | 0.85 | − 2.08 | +264,000 |
| 2 | S±4 | 2:4 | KKLWVS-INGK-KIWVSA | 0.49 | − 0.55 & − 0.53 | +88,000 |
| 3 | S±4 | 2:4 | KWVS-INGK-KIWE | 0.91 | − 2.46 | +596,000 |
| 4 | S±6 | 2:4 | KWLTVS-INGK-KITVWE | 0.95 | − 2.66 | +342,000 |
| 5 | -- | 2:4 | KKLTVS-INGK-KITVSA | 0.30 | n.a. | n.a. |
| 6 | S±4 | 4:6 | RWTV-NPATGK-ITWE | 0.83 | − 2.40 | +387,000 |
| 7 | S±4 | 4:6 | RAVWTV-NPATGK-ITWVIE | 0.34 | − 0.30 & − 0.62 | +395,000 |
| 8 | S±3 | 4:6 | RWV-NPATGK-IWE | < 0.61 | − 0.52 at W11 | +35,000 |
| 9 | S±2 | 4:6 | RVW-NPATGK-WIE | 0.97 | − 2.40 | +297,000 |
| 10 | S±2 | 3:5 | KKLTVW-SADGR-WITVSA | 0.78 | − 2.07 | + 282,000 |