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. 2017 Sep 26;117(19):12385–12414. doi: 10.1021/acs.chemrev.7b00259

Figure 13.

Figure 13

Supercooling water to low temperatures leads to a large divergent compressibility (top) and heat capacity (bottom). These quantities appear to diverge for temperatures approaching −45 °C. It is not clear whether this means water is approaching a typical spinodal point (i.e., the system must freeze to ice), or a point of phase transition between two liquid states. Data collected from refs (163) and (156).