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. 2017 Sep 26;117(19):12385–12414. doi: 10.1021/acs.chemrev.7b00259

Table 1. H2O Is More Cohesive than H2S, Despite Their Similar Structures, Because Water Forms Hydrogen Bonds.

property H2O H2S
molar mass [g mol–1] 18.015 34.081
boiling pointa [K] 373.12 212.85
melting pointa [K] 273.15 187.45
enthalpy of vaporizationb [kJ mol–1] 40.657 18.622
entropy of vaporizationb [J mol–1 K–1] 108.95 87.9
critical temperature [K] 647.1 373.2
critical pressure [MPa] 22.06 8.94
critical molar volume [cm3 mol–1] 55.9 98.5
critical density [kg m–3] 322 347
critical compressibility 0.229 0.284
specific heat capacityc (CV) [J mol–1 K–1] 74.539 26
specific heat capacityc (Cp) [J mol–1 K–1] 75.3 34.6
a

At 101.3 kPa.

b

At boiling.

c

At 25 °C and 101.3 kPa.