Table 1. Type of Experiments, Experimental Conditions, SOA Yields, Generated Clouds, and Instrumental Analysis (Mass Spectrometry) of SOA from Methacrolein Photooxidation.
[VOC]0a | [HONO]0 | [NO]0 | [NO2]0 | [O3]max | ΔM0b,c | T | RH | MS
measurementsd |
||||
---|---|---|---|---|---|---|---|---|---|---|---|---|
experiments | ppb | ppb | ppb | ppb | ppb | μg/m3 | °C | % | N clouds | AMS | GC-MS | ESI-HRMS |
blanks | ||||||||||||
BL-120115 | 0 | 137 | 195 | 104 | 2 | <0.3 | 19.6 | 0 | 0 | N | Y | Y |
BL-140115 | 0 | 232 | 162 | 108 | 3.2 | 22.5 | 20.5 | 71 | 1 | N | Y | Y |
control experiments | ||||||||||||
MC-020315 | 704 | 120 | 233 | 92 | 214 | 137 | 20.5 | 4–5 | 0 | N | Y | Y |
triphasic experiments | ||||||||||||
MT-180113 | 735 | 124 | 88 | 25 | 94 | 58.8 | 19.8 | 0 | 2 | Y | Y | Y |
MT-210113 | 927 | 150 | 118 | 81 | 123 | 65.8 | 19.4 | 5–3 | 2 | Y | Y | Y |
MT-230113 | 396 | 125 | 67 | 5 | 51 | 27.3 | 19.6 | 5–3 | 2 | Y | Y | N |
MT-130614 | 874 | 110 | 146 | 191 | 137 | 37 | 21.9 | 67 | 2 | Y | N | Y |
Measurement uncertainty is 15 ppb.
SOA concentration with effective density of 1.4 g/cm3.
Measurement uncertainty is 0.1 μg/m3.
Y = yes, N = no.