Table 3. Results of O-ATRP of MMA in Continuous Flow for the Synthesis of PMMA with Tunable Molecular Weights^a.

run no.	[MMA]:[DBMM]:[4]	Conv. (%)	Mw (kDa)	Mn (kDa)	Đ (Mw/Mn)	Theo. Mn (kDa)	I* (%)
1	[1000]:[20]:[1]	73	6.3	5.4	1.17	3.6	68
2	[1000]:[15]:[1]	48	3.7	3.0	1.24	3.2	108
3	[1000]:[10]:[1]	69	9.0	7.2	1.25	6.9	95
4	[1000]:[5]:[1]	76	25.2	19.3	1.30	15.3	79
5	[1000]:[2]:[1]	61	43.0	24.4	1.77	30.4	125
6	[250]:[10]:[1]	50	2.2	1.8	1.18	1.3	69
7	[500]:[10]:[1]	61	4.3	3.8	1.13	3.1	81
8	[1500]:[10]:[1]	85	18.9	13.6	1.39	12.7	94
9	[2000]:[10]:[1]	76	21.3	15.4	1.38	15.2	98
10	[3000]:[10]:[1]	79	29.9	20.5	1.46	23.6	115
11	[4000]:[10]:[1]	74	35.3	22.4	1.58	29.5	131
12	[5000]:[10]:[1]	65	37.0	22.2	1.67	32.6	147

^a[MMA]:[DBMM]:[4] = [X]:[Y]:[1]; 3.73 mM of 4, with 2:3 of MMA to DMA by volume and 160 cm tubing reactor irradiated by 3000 K fluorescent tubular lamp. Results were achieved using a 120 min residence time at a flow rate of 5.41 μL/min.