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. Author manuscript; available in PMC: 2018 Apr 11.
Published in final edited form as: Macromolecules. 2017 Mar 21;50(7):2668–2674. doi: 10.1021/acs.macromol.6b02791

Table 4. Monomer Scope of O-ATRP of Methacrylate Monomers Using Continuous Flow under Standard Conditionsa.

run no. Monomer Res. Time (min) Flow Rate (μL/min) Conv. (%) Mw (kDa) Mn (kDa) Đ (Mw/Mn) Theo. Mn (kDa) I* (%)
1 graphic file with name nihms868057t1.jpg 90 8.11 82 20.7 15.0 1.38 14.4 96
2 graphic file with name nihms868057t2.jpg 90 8.11 63 9.4 7.6 1.24 7.1 94
3 graphic file with name nihms868057t3.jpg 90 8.11 67 12.2 9.9 1.23 9.5 96
4 graphic file with name nihms868057t4.jpg 90 8.11 79 22.4 16.0 1.40 15.6 98
5 graphic file with name nihms868057t5.jpg 60 12.16 60 27.6 18.5 1.49 15.4 83
6 graphic file with name nihms868057t6.jpg 60 12.16 66 31.9 26.5 1.22 14.9 56
7 graphic file with name nihms868057t7.jpg 60 12.16 66 19.1 16.7 1.14 12.4 74
a

[Monomer]:[DBMM]:[PC 4] = [1000]:[10]:[1] 3.73 mM of 4, with 2:3 of MMA to DMA by volume and 160 cm tubing reactor irradiated by 3000 K fluorescent lamp.