. 2017 Aug 11;28(11):2319–2329. doi: 10.1007/s13361-017-1756-2

Table 1.

MS Acquisition Time Segments with Precursor and Product Ion Masses, Compound-Specific Declustering Potentials (DP), Collision Energy Potentials (CE), Collision Cell Exit Potentials (CXP) and Typical Fragment Ion Ratios from Various Matrices

Period start time (min)	Compound	Precursor ion m/z	Fragment Ion
Period start time (min)	Compound	Precursor ion m/z	Product m/z	Dwell time (ms)	DP (V)	CE (V)	CXP (V)	Quantitation (Q) Confirmation (C)	C/Q ion ratio
0.0	Cholesteryl ester	369	161	25	0	15	5.0	Q	0.39 (±0.05)
	Cholesteryl ester	369	81	25	0	20	5.0	C	0.39 (±0.05)
	Cholesteryl-d₇ palmitate (IS)	376	161	25	0	15	5.0	Q	0.31 (±0.01)
	Cholesteryl-d₇ palmitate (IS)	376	81	25	0	20	5.0	C	0.31 (±0.01)
0.4	Triglycerides	95	67	40	262	20	10.7	Q	0.51 (±0.04)
	Triglycerides	95	55	40	262	26	8.8	C	0.51 (±0.04)
	d₉₈-Tripalmitin (IS)	98	50	40	262	15	15.0	Q	0.65 (±0.05)
	d₉₈-Tripalmitin (IS)	106	74	40	262	25	15.0	C	0.65 (±0.05)
1.0	Free cholesterol	369	161	25	10	15	5.0	Q	0.67 (±0.06)
	Free cholesterol	369	81	25	10	20	5.0	C	0.67 (±0.06)
	d₇-Cholesterol (IS)	376	161	25	10	15	5.0	Q	0.64 (±0.03)
	d₇-Cholesterol (IS)	376	81	25	10	20	5.0	C	0.64 (±0.03)