Table 1. Summary of porosity parameters and comparison of R22 sorption performance for 1–3 .

Species	d a  a [Å2]	Cavity [Å3]	Void [%]	V c b [cm3 g–1]	S BET c [m2 g–1]	m 273 d [g g–1]	m 313 d [g g–1]	Δm e [g g–1]	D s [cm2 s–1]
1	6.6 × 5.8	9.4 × 9.9 × 13.2	63.4	0.798	2032	0.91	0.74	0.46 (0.13 bar)	5.6 × 10–7
2	3.0 × 5.8	9.4 × 9.9 × 13.2	60.7	0.723	1787	0.82	0.66	0.41 (0.11 bar)	5.1 × 10–7
3	6.6 × 10.0	9.4 × 9.9 × 15.9	69.5	1.071	2742	1.17	0.73	0.72 (0.52 bar)	7.3 × 10–7

^aThe apertures sizes along the a-axis.

^bThe pore volumes estimated from crystal structures.

^cMeasured BET surface areas.

^d m ₂₇₃ and m ₃₁₃: R22 uptakes at 273 and 313 K, 1 bar, respectively.

^eΔm: the highest working capacities between 273 and 313 K (at corresponding working pressures).