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. 2017 Oct 23;7:13844. doi: 10.1038/s41598-017-14098-1

Table 4.

Comparsion of MSPE-DLLME-HPLC/UV with other methods for the determination of industrial dyes.

Methods Analytes Analytes in common Matrix Extraction Solvent Volume (μL) LOD (μg∙L−1) Precision (RSD%) EF Recovery (%) References
MSPE-HPLC/FLD Malachite green, Gentian violet, Leuomalachite green, Leucogentian violet Malachite green Aquafarm water 0.09–0.22 2.7–6.5 91–95 87.0–92.8 3
MCPE-UV/Vis Malachite green, Crystal violet, Rhodamine B Malachite green, Crystal violet Tap water; Wastewater 2.2–5.1 4.5–8.39 29.26–85.47 59.5–115.0 25
S-FF-DSPE-UV/Vis Methylene blue Methylene blue Tap water; River water 2.5 2.9 135 99.0–109.0 26
DLLME-HPLC/UV Malachite green, Crystal violet Malachite green, Crystal violet Upriver water [C8MIM]PF6 80 0.030–0.086 7.6–9.4 254–276 71.7–97.2 27
SM-DLLME-UV/Vis Malachite green Malachite green Textile industry wastewater Decanoic acid -tetrahydrofuran 45500–500 4 1.8 52 85.3–108.6 28
MSPE-DLLME-HPLC/UV Malachite green, Crystal violet, Methylene blue Drinking water; Running water; Influent wastewater; Effluent wastewater; River water [Hpy]NTf2 70 0.03–0.05 1.2–2.6 484–502 86.1–100.3 Represented method