TABLE III.
Reaction Time/h | Monomer Conversion
|
BMAC mol %
|
||||||
---|---|---|---|---|---|---|---|---|
Mn | Mw | PDI | By GPC | By Yield | MAA mol % | By 1H NMR | By S-S Test | |
1 | 87 k | 138 k | 1.70 | 26 | 19 | 20.3 | 6.3 | 7.1 |
2 | 150 k | 210 k | 1.40 | 29 | 23 | 19.4 | 6.2 | 6.6 |
4 | 166 k | 347 k | 2.10 | 53 | 60 | 18.5 | 6.2 | 6.7 |
8 | 213 k | 495 k | 2.33 | 65 | 70 | 18.5 | 6.1 | 7.7 |
18 | 224 k | 475 k | 2.12 | 86 | 79 | 17.9 | 6.2 | 7.7 |