Table 2.
13C NMR spectroscopic data of 1–5 (δ in ppm)
No. | 1 a | 2 b | 3 b | 4 c | 5 c |
---|---|---|---|---|---|
1 | 157.8 s | 173.6 s | 165.8 s | 165.6 s | 165.3 s |
2 | 122.0 d | 31.6 t | 118.3 d | 118.1 d | 119.1 d |
3 | 133.5 d | 19.8 t | 143.1 d | 142.3 d | 141.3 d |
4 | 126.6 s | 111.6 s | 121.9 s | 120.7 s | 123.7 s |
5 | 157.7 s | 131.3 s | 144.1 s | 145.9 s | 145.9 s |
6 | 35.0 t | 28.0 t | 30.0 t | 35.2 t | 72.1 d |
7 | 33.1 d | 41.6 d | 35.3 d | 34.3 d | 42.2 d |
8 | 42.7 t | 78.8 d | 126.3 d | 125.8 d | 121.3 d |
9 | 40.4 t | 43.3 t | 51.8 t | ||
10 | 23.3 t | 27.3 t | 21.1 t | 12.5 q | 12.5 q |
11 | 24.3 t | 26.7 t | 26.9 t | 114.3 d | 115.0 d |
12 | 41.6 d | 38.1 d | 34.3 d | 137.3 s | 140.3 s |
13 | 61.2 s | 58.2 s | 58.3 s | 61.1 s | 55.7 s |
14 | 47.4 t | 42.4 t | 39.9 t | 50.7 t | 50.2 t |
15 | 26.0 d | 147.4 s | 137.8 s | 135.4 s | 136.6 s |
16 | 21.5 q | 115.1 t | 66.4 t | 22.7 q | 22.9 q |
17 | 24.2 q | ||||
N-CH3 | 38.0 q | 29.7 q |
aRecorded at 125 MHz in C5D5N
bRecorded at 125 MHz in CD3OD
cRecorded at 150 MHz in CD3OD