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Fig. 6. Schematic energy level diagram for direct detachment to the vibrational levels of the N1[T–H]˙ radical (left) and autodetachment from the vibrational levels of the DBS of N1[T–H]– (right). The EA of N1[T–H]˙ and the binding energy of the DBS are indicated. Autodetachment from the vibrational levels of the DBS to the neutral final states is indicated by the arrows. The vibrational levels of the DBS labeled with 1–16 correspond to peaks 1–16 in Fig. 3 and the neutral states labeled with letters are the same as those in Fig. 2, 4, 5, and Table 1.