Figure 2.
Activity (colored bars) and selectivity (black squares) A) of the catalytic hydroformylation of 1‐octene using different artificial metalloenzymes (the values for P1 have been magnified) and B) for the hydroformylation of alkenes with different chain lengths. Standard reaction conditions: 80 bar CO/H2 (1:1), 35 °C, 625 rpm, 0.5 mL of catalyst solution and 0.5 mL of alkene containing 9 % (v/v) n‐heptane and 1 % (v/v) diphenyl ether as internal standards. The Rh concentrations were determined by ICP‐MS and used to calculate the TONs, recorded values between 20 and 100 nmol Rh. Conversions and linear selectivities were obtained by GC analysis with a minimum of three runs. Error bars show the standard deviation. For further details, see Section S4.