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. 2015 Apr 27;6(6):3593–3598. doi: 10.1039/c5sc00215j

Table 1. Transcis ratios of compound 2, 3 and 4 before and after λ = 365 nm light irradiation in DMSOd6 at room temperature and half-lives of the cis-isomer at 30 °C and 37 °C in water.

Compound 2 3 4
No irradiation (DMSOd6, transcis) 97 : 3 97 : 3 97 : 3
365 nm light irradiation (DMSOd6, transcis) 38 : 62 10 : 90 4 : 96
Half-life in H2O at 30 °C (hours) >10 6.8 8.9
Half-life in H2O at 37 °C (hours) >10 2.5 5.8