Table 1. Hydrodehalogenation reaction of 1,1,1,3-tetrachloropropane catalyzed by Mo2 paddlewheel complexes.
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| Run | Cat. | Solvent | Additive | Yield a (%) |
| 1 | 1 | CD3CN | — | 4 |
| 2 | 2 | CD3CN | — | 47 |
| 3 | 3a | CD3CN | — | 64 |
| 4 | 3b | CD3CN | — | 9 |
| 5 | 3c | CD3CN | — | 1 |
| 6 | 4 | CD3CN | — | 31 |
| 7 | 5 | CD3CN | — | <1 |
| 8 | 3a | THF-d8 | — | 59 |
| 9 | 3a | C6D6 | — | 42 |
| 10 b | 3a | CD3CN | n Bu4NCl | 84 (73) |
| 11 | 7a | CD3CN | — | 71 |
| 12 b | 7a | CD3CN | n Bu4NCl | 85 |
| 13 b | 8a | CD3CN | n Bu4NCl | 32 |
| 14 | 9a | CD3CN | — | 85 |
aDetermined using 1H NMR measurements. Yield in parentheses was the isolated yield.
b n Bu4NCl (10 mol%) was added to the reaction mixture.