TABLE 3.
Polyaromatic Hydrocarbon (PAH) Analysis Using Liquid Chromatography/Mass Spectroscopy From 30 Archival DoDSR Samples
| Sample ID | Total PAH | Naphthalene | Fluorene | Phenanthrene | Anthracene | Fluor-anthene | Pyrene | Benz (a) Anthracene | Chrysene | Benzo (a) Pyrene | Benzo (ghi) Perylene |
|---|---|---|---|---|---|---|---|---|---|---|---|
| S053405966 | 3.5674 | 0.1412 | N/F | N/F | 0.1487 | N/F | N/F | N/F | N/F | 3.2776 | N/F |
| S080712445 | 0.9787 | 0.1565 | N/F | N/F | 0.1309 | N/F | N/F | N/F | N/F | 0.6913 | N/F |
| S122353014 | 3.2746 | 0.1925 | 0.0655 | 0.0567 | 0.2847 | N/F | N/F | N/F | N/F | 2.6752 | N/F |
| S156644116 | 0.3928 | 0.1367 | N/F | N/F | 0.1304 | N/F | N/F | N/F | N/F | 0.1256 | N/F |
| S169239333 | 3.9103 | 0.2103 | N/F | N/F | 0.0912 | 0.0153 | N/F | N/F | N/F | 3.5934 | N/F |
| S169424056 | 3.6422 | 0.1833 | N/F | N/F | 0.2327 | 0.0119 | N/F | N/F | N/F | 3.2143 | N/F |
| S172938259 | 2.7362 | 0.1644 | N/F | N/F | 0.054 | N/F | N/F | N/F | N/F | 2.4849 | N/F |
| S173820505 | 2.6796 | 0.1781 | N/F | N/F | 0.2454 | N/F | N/F | N/F | N/F | 2.2561 | N/F |
| S320055488 | 2.1464 | 0.1609 | N/F | N/F | 0.0761 | N/F | N/F | N/F | N/F | 1.9094 | N/F |
| S321462178 | 1.1959 | 0.1854 | N/F | N/F | 0.284 | N/F | N/F | N/F | N/F | 0.7265 | N/F |
| S383498374 | 2.2817 | 0.1627 | N/F | N/F | 0.1111 | N/F | N/F | N/F | N/F | 1.9368 | 0.0711 |
| S456732067 | 1.1899 | 0.1352 | N/F | N/F | 0.1708 | N/F | N/F | N/F | N/F | 0.8839 | N/F |
| S500933196 | 158.358 | 0.1133 | 0.0224 | 0.0145 | 0.1759 | 0.0562 | 0.0085 | N/F | N/F | 37.2643 | 0.2594 |
| S576739980 | 1.9407 | 0.1914 | N/F | N/F | 0.2136 | N/F | N/F | N/F | N/F | 1.5357 | N/F |
| S624913446 | 2.3831 | 0.1366 | 0.0075 | 0.0055 | 0.1455 | 0.0075 | 0.0115 | N/F | N/F | 2.069 | N/F |
| S685083601 | 1.248 | 0.1667 | N/F | N/F | 0.1175 | N/F | N/F | 0.1333 | 0.1455 | 0.685 | N/F |
| S695344016 | 2.6218 | 0.1625 | 0.0326 | 0.0249 | 0.2434 | 0.0083 | N/F | N/F | N/F | 2.1084 | 0.042 |
| S716543256 | 1.8196 | 0.1803 | N/F | N/F | 0.1134 | N/F | N/F | N/F | N/F | 1.526 | N/F |
| S748323523 | 3.9861 | 0.1193 | N/F | N/F | 0.1526 | 0.018 | 0.0293 | 0.0379 | 0.0413 | 3.5876 | N/F |
| S758598913 | 7.3575 | 0.1541 | 0.0073 | 0.0071 | 0.1292 | 0.0273 | 0.0143 | N/F | N/F | 6.0341 | N/F |
| S786911942 | 1.043 | 0.1203 | N/F | N/F | 0.1925 | N/F | N/F | N/F | N/F | 0.7303 | N/F |
| S789635792 | 1.1289 | 0.2359 | N/F | N/F | 0.1576 | N/F | N/F | N/F | N/F | 0.7355 | N/F |
| S799412327 | 1.7397 | 0.1623 | N/F | N/F | 0.1571 | N/F | N/F | N/F | N/F | 1.4203 | N/F |
| S802483786 | 3.8096 | 0.1241 | N/F | N/F | 0.2445 | 0.0519 | 0.0704 | 0.0786 | 0.0537 | 3.0602 | 0.1262 |
| S829657159 | 5.899 | 0.2207 | N/F | N/F | 0.1694 | N/F | N/F | N/F | N/F | 5.5089 | N/F |
| S846210194 | 2.7672 | 0.1062 | 0.0203 | 0.0115 | 0.1987 | 0.0055 | N/F | 0.0319 | 0.0348 | 2.3583 | N/F |
| S930920676 | 2.8547 | 0.1354 | 0.0261 | 0.0161 | 0.2182 | 0.0111 | N/F | N/F | N/F | 2.4478 | N/F |
| S938451005 | 2.2668 | 0.1237 | N/F | N/F | 0.2258 | N/F | N/F | N/F | N/F | 1.9174 | N/F |
| S961642526 | 1.9535 | 0.1748 | N/F | N/F | 0.0653 | N/F | N/F | N/F | N/F | 1.7133 | N/F |
| S974027464 | 3.88 | 0.1623 | 0.0883 | 0.074 | 0.2198 | 0.0115 | 0.0112 | N/F | N/F | 3.3129 | N/F |
Total and specific PAHs were detected in DoDSR samples (highlighted samples are cotinine positive). Naphthalene, anthracene, and Benzo[a]pyrene were detected in all samples, whereas acenaphthylene, Benzo(b)fluoranthene, Benzo(k)fluoranthene, Indeno(123cd)ppyrene were assayed but not detected.