Figure 6.
Transition temperature T C, as a function of pore diameter D’, along with distinctive transition temperatures reported previously for water confined in MCM-41. The diameter of the SWCNT pore was defined by where t ≈ 0.3 − 0.4 nm, the thickness of the SWCNT wall. AC: melting temperatures of ice Ih (dotted gray line) and heat-capacity maximum temperatures (green squares with crosses) obtained by adiabatic calorimetry for MCM-4155; XRD: melting temperatures of ice Ih obtained from XRD patterns of MCM-4156; NMR: anomalous temperatures obtained from NMR relaxation times in MCM-4149; QENS: anomalous temperatures obtained from quasielastic neutron scattering measurements48,50. The closed red circles were obtained from XRD patterns in ref.22 and Supplementary Fig. S4 in the present paper.