Table 2.
Optimized MS/MS parameters for the studied mycotoxins: retention time, quantitation transition, confirmation transition, declustering potential (DP), collision energy (CE), and collision cell exit potential (CXP).
| Mycotoxin | Retention Time (min) | Quantitation Transition | Confirmation Transition | DP (V) | CE (V) | CXP (V) |
|---|---|---|---|---|---|---|
| EN A | 13.1 | 699.4 > 210.1 | 699.4 > 228.2 | 76 | 35 | 14 |
| EN A1 | 12.2 | 685.4 > 210.2 | 685.4 > 214.2 | 66 | 37 | 8 |
| EN B | 11.1 | 657.3 > 196.1 | 657.3 > 214.0 | 51 | 39 | 8 |
| EN B1 | 11.6 | 671.2 > 214.1 | 671.2 > 228.1 | 66 | 61 | 10 |
| BEA | 11.8 | 801.2 > 784.1 | 801.2 > 244.1 | 116 | 27 | 10 |
| AFB1 | 8.0 | 313.1 > 241.0 | 313.1 > 284.9 | 46 | 41 | 4 |
| AFB2 | 7.9 | 315.1 > 286.9 | 315.1 >259.0 | 81 | 33 | 6 |
| AFG1 | 7.8 | 329.0 > 243.1 | 329.0 > 311.1 | 76 | 39 | 6 |
| AFG2 | 7.7 | 331.1 > 313.1 | 331.1 > 245.1 | 61 | 27 | 6 |
| OTA | 9.3 | 404.3 > 102.1 | 404.3 > 239.0 | 55 | 97 | 6 |
| ZEA | 9.4 | 319.0 > 301.0 | 319.0 > 282.9 | 26 | 15 | 10 |