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Representative thiotetronate antibiotics biosynthetic gene clusters and metabolites. a) Gene organization of the thiotetroamide (ttm) and thiolactomycin (tlm) gene clusters from Streptomyces afghaniensis NRRL 5621 and Salinispora pacifica CNS 863, respectively.[18] b) Chemical structures of the major products of the ttm (thiotetroamide C, 1) and tlm (thiolactomycin, 2, and its analogues 3–5) pathways.
