Table 2. Coupling of Aryl Halides with Primary Alkylamines Using (CyPF-^tBu)PdCl₂ 1^a.

entry	halide	product	catalyst loading (%)	conditions	yield (%)b
1			0.001	110 °C, 24 h	92
2			0.01	110°C,24 h	85
3			0.05	100°C,24 h	88
4			0.005	80 °C, 36 h	86
5			0.005	100°C,36 h	74
6c			0.005	110 °C, 12 h	87
7			0.05	100°C,30 h	88
8			0.05	100°C,24 h	96
9			0.05	110 °C, 24 h	70

^aReactions conducted with a 1:1 ratio of metal to ligand, 1 mmol ArX, 1.2 equiv amine, and 1.4 equiv NaO-^tBu in 1 mL DME.

^bIsolated yield.