Table 1.

Orbital compositions of SnS₂ conduction band

		s (%)		p x,y (%)		p z (%)
		Sn	S	Sn	S	Sn	S
Γ	A1,2	48.0	0.26	0	47.5	0	1.55
	B1,2	0.23	5.55	32.7	29.2	16.6	15.6
Μ	A1,2	48.1	2.31	0	42.6	0	7.08
	B1,2	0	11.6	13.4	17.6	31.1	26.3

Normalized orbital compositions (in %) of regions A_1,2 and B_1,2 at two representative high-symmetry points in the Brillouin zone. Dominant orbitals contributing include s, p _x, p _y, and p _z for both Sn and S atoms at Γ and M. Sn d orbitals contribute less than 3% of the total orbital contributions