. Author manuscript; available in PMC: 2018 Nov 13.

Published in final edited form as: Angew Chem Int Ed Engl. 2017 Oct 17;56(46):14384–14388. doi: 10.1002/anie.201707872

Table 1.

A comparison of the redox potentials, zero-field splitting and second-order rate constants (k₂) with C₆H₁₂ and PhSMe for 1, 3d and [Fe^IV(O)(TMC)(CH₃CN)]²⁺

Complex	D [cm⁻¹]	E(Fe^IV/III) vs SCE	k₂^[a](C₆H₁₂) [M⁻¹ s⁻¹]	k₂^[a](PhSMe) [M⁻¹ s⁻¹]
1	35±3	0.90	1 × 10⁻²	2.5 × 10²
3d	-	0.37	no reaction	4.0 × 10⁻³
[Fe^IV(O)(TMC)(CH₃CN)]^{2+ [1a]}	26.95 ±0.15	0.39	no reaction	1.3 × 10⁻³

^[a]

@ −40 °C