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. 2017 Nov 9;7:15194. doi: 10.1038/s41598-017-15209-8

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© The Author(s) 2017

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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GC/MS characterization of the enzymatically-generated degradation products. RI is the experimental Kovats retention index of the molecule and m/z is the mass-to-charge ratio of the base peak fragment detected for each molecule. The leaving group and the corresponding degradation product are emphasized in red. (a) Paraoxon-ethyl (CAS 311-45-5) led to 4-nitrophenol (CAS 100-02-7); (b) Parathion-ethyl (CAS 56-38-2) led to 4-nitrophenol (CAS 100-02-7); (c) Diazinon (CAS 333-41-5) led to 6-methyl-2-propan-2-yl-1H-pyrimidin-4-one (CAS 2814-20-2); (d) Fenitrothion (CAS 122-14-5) led to 3-methyl-4-nitrophenol (CAS 58864-63-4).