Table 1. Overview of the Polymer Composition, Number-Average Molecular Weight (Mn), Molar Mass Dispersity (ĐM), and Dodecyl Equivalents of Px–y.
BTAa (mol %) | dodecyla (mol %) | Jeffamine M-1000a (mol %) | Mn, SECb (kg mol–1) | ĐMb | dodecyl equiv.c | |
---|---|---|---|---|---|---|
P0–0 | 0 | 0 | 100 | 22.8 | 1.16 | 0 |
P0–20 | 0 | 20 | 80 | 22.6 | 1.18 | 20 |
P5–15 | 5 | 15 | 80 | 22.4 | 1.24 | 30 |
P10–0 | 10 | 0 | 90 | 22.3 | 1.20 | 30 |
P10–10 | 10 | 10 | 80 | 22.7 | 1.23 | 40 |
P15–5 | 15 | 5 | 80 | 23.9 | 1.18 | 50 |
P20–0 | 20 | 0 | 80 | 23.8 | 1.18 | 60 |
Based on the feed ratio and confirmed via 19F NMR spectroscopy.
Determined using SEC in DMF.
Based on the assumption that one BTA approximately equals three dodecyl groups in terms of carbon content, so dodecyl equivalents = mol %dodecyl,(y) + 3·mol %BTA,(x).