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. Author manuscript; available in PMC: 2017 Nov 16.
Published in final edited form as: Inorg Chem. 2017 May 30;56(12):6838–6848. doi: 10.1021/acs.inorgchem.7b00125

Table 1.

Measurement of Metal/TTP-2D Stoichiometry Using ICP-MS

Cu stoichiometry
Zn stoichiometry
Cu-TTP-2D 3.1 (±0.27a, ± 0.13b) Zn-TTP-2D 2.3 (±0.41,a 0.10b)
apo-TTP-2D 0.034 (±0.013,a ±0.004b) apo-TTP-2D 0.004 (±0.005,a 0.001b)
bufferc 0.057 (±0.097,a ±0.028b) bufferc 0.027 (±0.010,a 0.002b)
a

SD, standard deviation.

b

SEM, estimated standard error of the mean (n = 12).

c

Conditions: buffer 200 mM HEPES, 100 mM NaCl, pH 7.5 with 5 equiv of Cu or Zn.