Table 1.
List of MOFs and their defect scenarios leading to notable methane uptake enhancements
| MOF CSD Refcode | Modulators used | % of linker vacancies | Uptake—defect 65 bar (v STP/v) | Uptake—pristine 65 bar (v STP/v) | Uptake enhancement 65 bar (v STP/v) | % of uptake enhancement |
|---|---|---|---|---|---|---|
| PAMHIW54 | Formate | 8.33 | 192.09 | 123.38 | 68.71 | 55.69 |
| PAMHIW | Water, OH | 8.33 | 185.43 | 123.38 | 62.05 | 50.29 |
| AXUBOL (IN) | OH (water X) | 5.56 | 171.52 | 112.56 | 58.95 | 52.37 |
| AXUBOL (BDC) | Formate | 5.56 | 169.13 | 112.56 | 56.56 | 50.25 |
| AXUBOL (BDC) | Water, OH | 5.56 | 169.04 | 112.56 | 56.48 | 50.17 |
| KOCWEF (1) | OH (water X) | 6.25 | 107.03 | 71.65 | 35.38 | 49.38 |
| HOMZEP55 | Water, OH | 8.33 | 164.35 | 129.78 | 34.57 | 26.64 |
| UTEWOG56 | Water, OH | 6.25 | 197.94 | 163.43 | 34.50 | 21.11 |
| UTEWUM56 | Water, OH | 6.25 | 195.87 | 163.19 | 32.68 | 20.03 |
| XENZUN57 | OH | 6.25 | 138.01 | 105.43 | 32.57 | 30.90 |
| XENZUN | Formate | 6.25 | 137.38 | 105.43 | 31.95 | 30.30 |
| JEWYAM58 | Water, OH | 6.25 | 185.23 | 154.46 | 30.77 | 19.92 |
| KOCWEF (2) | Formate, tetrazolate | 6.25 | 101.78 | 71.65 | 30.13 | 42.05 |
| REGYOT59 | Water, OH | 6.25 | 193.98 | 166.00 | 27.98 | 16.85 |
| QAGQEW60 | Formate | 6.25 | 193.73 | 165.82 | 27.91 | 16.83 |
| KOCWEF (2) | Water, OH | 6.25 | 99.38 | 71.65 | 27.73 | 38.69 |
| REGYOT | Formate | 6.25 | 193.50 | 166.00 | 27.49 | 16.56 |
| QAGQEW | Water, OH | 6.25 | 192.09 | 165.82 | 26.27 | 15.84 |
| ABEMIF61 | Water, OH | 6.25 | 162.62 | 136.95 | 25.67 | 18.74 |
| VEXYON62 | Water, OH | 6.25 | 178.52 | 152.98 | 25.54 | 16.70 |
| MUWQEB63 | Water, OH | 6.25 | 181.02 | 157.20 | 23.81 | 15.15 |
Entries are presented in the order of highest uptake enhancement to lowest uptake enhancement in (v STP/v) at 65 bar, 298 K