. 2017 Oct 12;139(45):16228–16234. doi: 10.1021/jacs.7b07489

Table 1. Gibbs Free Energy of formation of Co^II and Co^I by Oxidative and Reductive Electron Transfer Pathways^a.

E_CB^N2,V (NHE) in vacuum	E(N2^•–), V (NHE) in vacuum	E(Co^III/Co^II), V (NHE) in ACN	E(Co^II/Co^I), V (NHE) in ACN	ΔG₁°, eV^b	ΔG₂°, eV^b	ΔG₃°, eV^b	ΔG₄°, eV^b
–1.52	–2.31	–0.43	–0.88	–1.09	–0.64	–1.88	–1.43

The N2-COF energy levels are the calculated values for a model hexagon with hydrazone termination.⁹E(Co^III/Co^II) and E(Co^II/Co^I) potential values have been obtained from ref (25).

Calculations are as follows: Inline graphic , , , .

Table 1. Gibbs Free Energy of formation of CoII and CoI by Oxidative and Reductive Electron Transfer Pathwaysa.

Table 1. Gibbs Free Energy of formation of Co^II and Co^I by Oxidative and Reductive Electron Transfer Pathways^a.