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Selected Physical Properties for the CoII—OH Complexes.
| λmax (nm), (E, cm−1) | ν(O—H) (FWHM, cm−1) | E1/2 (Ea) (V vs [FeCp2]+/0) | ΔE (V), ia/ic | |
|---|---|---|---|---|
| [CoIITST(OH)]2− | 890, (11,200) | 3574 (24) | N/A (−0.52) | – |
| [CoIIH1tol(OH)]2− | 820, (12,200) | 3602, 3581 (16) | −0.905 (−0.58) | 0.485, 1.04 |
| [CoIIH22tol(OH)]2− | 767, (13,000) | 3625 (9) | −0.828 (−0.71) | 0.380, 1.12 |
| [CoIIH3buea(OH)]2− | 710, (14,100) | N/A | −1.28 (−1.17) | 0.215, 1.07 |
