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. 2017 Oct 11;56(46):14591–14595. doi: 10.1002/anie.201708947

Table 1.

Catalyst screening for the reaction of 1 a with allene 5 a.[a] Inline graphic

Entry Catalyst 6 a Yield [%][b]
1 A 74 (66)[c]
2 B 55
3 C 61
4 D 55
5 E 31
6 F 57
7 G [d]

[a] Reaction conditions: 1 a (0.1 m in DCE), 5 a (2.0 equiv), catalyst (5 mol %), 120 °C, 8 h. [b] The yield was determined by 1H NMR spectroscopy with 1,3,5‐trimethoxybenzene as an internal standard. [c] The yield of the isolated product is given in parentheses. [d] Not detected. Cy=cyclohexyl, DCE=1,2‐dichloroethane, Tf=trifluoromethanesulfonyl. graphic file with name ANIE-56-14591-g008.jpg