Skip to main content
. 2017 Sep 7;9(20):3821–3826. doi: 10.1002/cctc.201700779

Table 1.

Photocatalytic oxidation of some C−H bonds.[a] Inline graphic

Entry Substrate Product Product [mm] Selectivity [%][b] TON TOF [h−1]
1 graphic file with name CCTC-9-3821-g008.jpg graphic file with name CCTC-9-3821-g009.jpg 86.6 89.4 37.1 1.5
2 graphic file with name CCTC-9-3821-g010.jpg graphic file with name CCTC-9-3821-g011.jpg 58.8 80 25.2 1.0
3 graphic file with name CCTC-9-3821-g012.jpg graphic file with name CCTC-9-3821-g013.jpg 8.6 69.5 3.7 0.2
4 graphic file with name CCTC-9-3821-g014.jpg graphic file with name CCTC-9-3821-g015.jpg 21.4 76 9.2 0.4
5 graphic file with name CCTC-9-3821-g016.jpg graphic file with name CCTC-9-3821-g017.jpg 14.5 n.d. 6.2 0.3
6 graphic file with name CCTC-9-3821-g018.jpg graphic file with name CCTC-9-3821-g019.jpg 17 n.d. 7.3 0.3
7 graphic file with name CCTC-9-3821-g020.jpg graphic file with name CCTC-9-3821-g021.jpg 34.3 80.7 14.7 0.6
8[c] graphic file with name CCTC-9-3821-g022.jpg graphic file with name CCTC-9-3821-g023.jpg 195 96 41.8 0.9
9 graphic file with name CCTC-9-3821-g024.jpg graphic file with name CCTC-9-3821-g025.jpg 29.3+38.8 n.d. 12.6+16.6 0.5+0.7
10 graphic file with name CCTC-9-3821-g026.jpg graphic file with name CCTC-9-3821-g027.jpg 94.3 n.d. 40.4 1.7
11 graphic file with name CCTC-9-3821-g028.jpg graphic file with name CCTC-9-3821-g029.jpg 14.4 n.d. 6.2 0.3
12 graphic file with name CCTC-9-3821-g030.jpg graphic file with name CCTC-9-3821-g031.jpg 19.2 n.d. 8.2 0.34
13[d] graphic file with name CCTC-9-3821-g032.jpg graphic file with name CCTC-9-3821-g033.jpg 7.5/0.6[e] n.d. 3.2/0.4[e] 0.13/0.02[e]
14[d] graphic file with name CCTC-9-3821-g034.jpg graphic file with name CCTC-9-3821-g035.jpg 11.9/4.4[e] n.d. 5.1/3.1[e] 0.21/0.1[e]

[a] Conditions: alkane/water [c(SAS)aq=1 mm]=3:7, O2 atmosphere, T=30 °C, λ>400 nm, reaction time: 24 h; values correspond to the concentration in the organic phase; n.d.=not determined; TON=molproduct×molSAS −1; TOF=TON×24 h−1. [b] Selectivity was calculated on the basis of the sum of the aldehyde/ketone products and intermediates alcohols. [c] c(SAS)aq=2 mm, t=48 h. [d] Minor amounts of side products were detected by GC (Figures S16 and S17). [e] Product concentration in water phase.