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. 2017 Sep 7;9(20):3821–3826. doi: 10.1002/cctc.201700779

Table 2.

Photocatalytic oxidation of some alcohols.[a] Inline graphic

Entry Substrate Product Product [mm] TON TOF [h−1]
1 graphic file with name CCTC-9-3821-g037.jpg graphic file with name CCTC-9-3821-g038.jpg 989 424 17.7
2 graphic file with name CCTC-9-3821-g039.jpg graphic file with name CCTC-9-3821-g040.jpg 87.5 37.5 1.6
3 graphic file with name CCTC-9-3821-g041.jpg graphic file with name CCTC-9-3821-g042.jpg 330 142 5.9
4 graphic file with name CCTC-9-3821-g043.jpg graphic file with name CCTC-9-3821-g044.jpg 235 101 4.2
5 graphic file with name CCTC-9-3821-g045.jpg graphic file with name CCTC-9-3821-g046.jpg 179/15.7[c] 76.8/11.0[c] 3.2/0.5[c]
6 graphic file with name CCTC-9-3821-g047.jpg graphic file with name CCTC-9-3821-g048.jpg 359/63.6[c] 154/44.5[c] 6.4/1.9[c]
7 graphic file with name CCTC-9-3821-g049.jpg graphic file with name CCTC-9-3821-g050.jpg 440 188 7.8
8[b] graphic file with name CCTC-9-3821-g051.jpg graphic file with name CCTC-9-3821-g052.jpg 307 65.7 2.7
9 graphic file with name CCTC-9-3821-g053.jpg graphic file with name CCTC-9-3821-g054.jpg 412 177 7.4
10 graphic file with name CCTC-9-3821-g055.jpg graphic file with name CCTC-9-3821-g056.jpg 514 220 9.2
11 graphic file with name CCTC-9-3821-g057.jpg graphic file with name CCTC-9-3821-g058.jpg 27.5 11.8 0.5
12 graphic file with name CCTC-9-3821-g059.jpg graphic file with name CCTC-9-3821-g060.jpg 69.9 30.0 1.3
13 graphic file with name CCTC-9-3821-g061.jpg graphic file with name CCTC-9-3821-g062.jpg 44.3 19.0 0.8

[a] Conditions: alcohol/water [c(SAS)aq=1 mm]=3:7, O2 atmosphere, T=30 °C, λ>400 nm, reaction time: 24 h; values correspond to the concentration in the organic phase; TON=molproduct×molSAS −1; TOF=TON×24 h−1. [b] c(SAS)aq=2 mm was used, t=48 h. [c] Product concentration in water phase.