Table 2.

Substrate Scope of the ortho-to-Fluorine C(sp²)–H Borylation of 2-Substituted Fluoroarenes Catalyzed by 1^a

^aReaction conditions: arene (0.55 mmol), B₂Pin₂ (0.55 mmol), 1 (0.0275 mmol, 5 mol %), THF (1 mL), 50 °C. Reported numbers are isolated yields after column chromatography. Numbers in parentheses correspond to the regioselectivities (ortho:meta:para ratio) determined by ¹⁹F NMR spectroscopy.