Table 2.
Substrate scope of aromatic ring containing compounds
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Selective α-hydroperoxidation/lactonization of aromatic cyclic/linear ethers by 1O2. All substrates (0.35 M, in DCM-ACN (9:1)) were irradiated by blue LEDs (40 mW cm−2) for 12 h at room temperature in the presence of 1 × 10−5 M of meso-TPP, ~ 1 atm O2 balloon, and in the presence of γ-Al2O3. All yields were reported based isolated yields (after removal of the unreacted starting substrate)
[a] % of yield was expressed with respect to the amount of starting materials. Beside the listed products, the rest of material is unreacted starting substrate
[b] Conv % = 100%−(% recovered starting substrate)