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. Author manuscript; available in PMC: 2017 Nov 28.
Published in final edited form as: Food Chem Toxicol. 2015 Apr 28;82:50–58. doi: 10.1016/j.fct.2015.04.016

Table 3.

Levels of five tobacco-specific N-Nitrosamines (n=3) present in various rapé samples.

Product NAB NAT NNAL NNK NNN NNN+NNK Total TSNAs*

Average (ng/g, wet weight; n=3)
Rapé (manufactured, non-tobacco)
Rapé Cacitral <LOD <LOD <LOD <LOD <LOD <LOD <LOD
Rapé Guarany Cristal <LOD <LOD <LOD <LOD 13.2 n.a. 13.2

Rapé (manufactured, tobacco-containing)
Rapé Guarany Especial 376 2570 554 3300 13000 16300 19800
Rapé Guarany Especial (Canela) 364 2510 530 3250 12600 15900 19300
Rapé Guarany Cravo 58.1 735 49.4 133 739 872 1710
Rapé Moeda Especial 135 2080 118 1160 2390 3540 5870
Rapé Caratinga Mentolado 742 7290 277 1360 14500 15800 24200
Rapé Caratinga Imburana 268 2440 166 670 2450 3120 5990
Rapé Araçá Cravo e Canela 237 2610 132 425 2150 2576 5556
Rapé Moeda Girassol 158 1740 38.2 251 1790 2040 3980
Rapé Real (flavored) 86.1 1180 42.4 131 1020 1150 2460
Rapé Real(unflavored) 157 1700 50.3 232 1440 1680 3580

Rapé (custom-made, tobacco-containing)
Rapé Kashinawá 45.2 437 12.9 470 152 621 1120
Rapé Nu-nu 22.9 21.3 2.35 12 29 42 88

Minimum detected 9.16 6.85 2.35 3.99 13.2 17.2 36.7
Maximum detected 742 7290 554 3300 14500 16300 24200

Note: Total TSNAs is the sum of NAB, NAT, NNAL, NNK and NNN concentrations; n.a. = not applicable

TSNA analytes in this study, included N-nitrosonornicotine (NNN), 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanone (NNK), N-nitrosoanatabine (NAT), N-nitrosoanabasine (NAB), and 4-(methylnitrosamino)-1-(3-pyridyl)-1-butanol (NNAL).