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. Author manuscript; available in PMC: 2017 Dec 1.
Published in final edited form as: J Am Chem Soc. 2017 Oct 4;139(41):14372–14375. doi: 10.1021/jacs.7b08161

Figure 1.

Figure 1

(a) UV–vis spectra of [FeV(NTs)(TAML)] − (1, black line) and [FeV(NTs)(TAML+•)] (2, blue line); 2 was synthesized by reacting 1 (0.20 mM) with 1.0 equiv of [Ru(bpy)3]3+ (0.20 mM) in CH3CN at −40 °C. Inset shows plot of the absorbance change at 750 nm due to 2 upon addition of [Ru(bpy)3]3+ to 1 (0.20 mM) in increment of 0.2 equiv. (b) Mössbauer spectra (black dotted lines) with fits (blue lines) for 2 recorded at 4.2 K and 0, 4, and 7 T.