Table 3.

Measured values for k′, D_m, D_eff, and $\frac{D_{\mathit{eff}}}{D_m}$ along with the conditions used for the Hypercarb column (4.6 mm × 100 mm, 3 μm) at 30 °C.

Analyte	Mobile phase	k′	Dm (cm2/s)	Deff (cm2/s)	$\frac{D_{\mathit{eff}}}{D_m}$
Acetone	5/95 Water/MeOH	0	2.61 ± 0.05 × 10−5	1.25 × 10−5	0.48
2-MHA	5/95 Water/MeOH	0.87	9.62 ± 0.17 × 10−6	2.9 × 10−6	0.30
Hippuric acid	5/95 Water/MeOH	1.95	9.51 ± 0.17 × 10−6	2.0 × 10−6	0.21
3-MHA	5/95 Water/MeOH	4.72	9.45 ± 0.17 × 10−6	1.5 × 10−6	0.16
4-MHA	5/95 Water/MeOH	6.40	9.25 ± 0.16 × 10−6	1.4 × 10−6	0.15
4-MHA	25/75 Water/MeOH	16.3	5.82 ± 0.10 × 10−6	7.2 × 10−7	0.12
4-MHA	40/60 Water/MeOH	41.2	4.81 ± 0.09 × 10−6	4.7 × 10−7	0.10