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. 2017 Dec 6;13:108. doi: 10.1186/s13007-017-0258-3

Table 2.

Identification of standard anti-oxidant compounds in the EtOAc extract of mulberry fruit using UHR 15-T FT-ICR mass spectrometry

# Standard name Formula Calc. [M-H] [m/z] Observed [M-H] [m/z] Error [mDa] S/N
1 Gentisic acid C7H6O4 153.01933 153.01933 0.00 24
2 Gallic acid C7H6O5 169.01425 169.01426 0.01 10.1
3 Caffeic acid C9H8O4 179.03498 179.03498 0.00 18.5
4 Luteolin C15H10O6 285.04046 285.04047 − 0.01 372.3
5 Kaempferol C15H10O6 285.04046 285.04047 − 0.01 372.3
6 Quercetin C15H10O7 301.03538 301.03538 0.00 710.1
7 Dihydroquercetin C15H12O7 303.05103 303.05104 − 0.01 370.6
8 Chlorogenic acid C16H18O9 353.08781 353.08780 0.01 191.4
9 Quercitrin C21H20O11 447.09329 447.09326 0.03 53.9
10 Quercetin-3-o-glucoside C21H20O12 463.08820 463.08820 0.00 467.9
11 Rutin C27H30O16 609.14611 609.14610 0.01 245.5

A UHR mass profile of the compounds in EAEM was obtained and all 11 SAOx were detected at high mass accuracy with measurement error < 0.05 mDa