Table 2.
Identification of standard anti-oxidant compounds in the EtOAc extract of mulberry fruit using UHR 15-T FT-ICR mass spectrometry
| # | Standard name | Formula | Calc. [M-H]− [m/z] | Observed [M-H]− [m/z] | Error [mDa] | S/N |
|---|---|---|---|---|---|---|
| 1 | Gentisic acid | C7H6O4 | 153.01933 | 153.01933 | 0.00 | 24 |
| 2 | Gallic acid | C7H6O5 | 169.01425 | 169.01426 | 0.01 | 10.1 |
| 3 | Caffeic acid | C9H8O4 | 179.03498 | 179.03498 | 0.00 | 18.5 |
| 4 | Luteolin | C15H10O6 | 285.04046 | 285.04047 | − 0.01 | 372.3 |
| 5 | Kaempferol | C15H10O6 | 285.04046 | 285.04047 | − 0.01 | 372.3 |
| 6 | Quercetin | C15H10O7 | 301.03538 | 301.03538 | 0.00 | 710.1 |
| 7 | Dihydroquercetin | C15H12O7 | 303.05103 | 303.05104 | − 0.01 | 370.6 |
| 8 | Chlorogenic acid | C16H18O9 | 353.08781 | 353.08780 | 0.01 | 191.4 |
| 9 | Quercitrin | C21H20O11 | 447.09329 | 447.09326 | 0.03 | 53.9 |
| 10 | Quercetin-3-o-glucoside | C21H20O12 | 463.08820 | 463.08820 | 0.00 | 467.9 |
| 11 | Rutin | C27H30O16 | 609.14611 | 609.14610 | 0.01 | 245.5 |
A UHR mass profile of the compounds in EAEM was obtained and all 11 SAOx were detected at high mass accuracy with measurement error < 0.05 mDa