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. Author manuscript; available in PMC: 2018 Mar 6.
Published in final edited form as: Angew Chem Int Ed Engl. 2017 Jan 27;56(11):2862–2879. doi: 10.1002/anie.201609054

Scheme 19.

Scheme 19

(a) Redox isomerization of propargyl alcohol 52 (b) Deuterium labeling study and proposed mechanism of ruthenium-catalyzed redox isomerization of propargyl alcohols