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. Author manuscript; available in PMC: 2017 Dec 28.
Published in final edited form as: Chem Rev. 2016 Dec 8;116(24):15035–15088. doi: 10.1021/acs.chemrev.6b00488

Scheme 56.

Scheme 56

Hatakeyama Completes Phoslactomycin B Using a Sharpless Asymmetric Dihydroxylation To Install the C8 and C9 Stereocenters and a Stille Cross-Coupling To Unite the Cyclohexyl Fragment