Table 1.
Number | Compound | RIa | Compositionb (%) | ||
---|---|---|---|---|---|
Leaves | Inflorescences | ||||
Dry material | Essential oil | ||||
1 | α-Thujene | 924 | 0.2 | 0.2 | — |
2 | α-Pinene | 940 | 46.0 | 40.1 | 16.3 |
3 | Camphene | 957 | 0.2 | 0.5 | 0.3 |
4 | Sabinene | 978 | 9.6 | 9.7 | 12.0 |
5 | β-Pinene | 982 | 0.8 | 0.7 | — |
6 | β-Myrcene | 991 | 2.9 | 1.5 | 1.7 |
7 | α-Phellandrene | 1006 | 1.1 | 0.8 | 1.3 |
8 | 3-Carene | 1013 | 0.1 | 0.2 | — |
9 | α-Terpinene | 1018 | — | — | 0.2 |
10 | p-Cymene | 1026 | 0.6 | 0.2 | — |
11 | β-Phellandrene | 1031 | 24.6 | 13.9 | 26.0 |
12 | Z-β-Ocimene | 1046 | 0.3 | 0.4 | 0.6 |
13 | Butyl-2-methylbutanoate | 1048 | 0.2 | — | — |
14 | E-β-Ocimene | 1055 | 0.3 | 0.3 | — |
15 | γ-Terpinene | 1059 | 0.2 | 0.0 | 0.4 |
16 | cis-Sabinene hydrate | 1071 | — | 0.1 | — |
17 | α-Terpinolene | 1088 | 0.8 | — | 0.2 |
18 | Linalool | 1094 | 0.3 | 0.1 | — |
19 | trans-para-Mentha-2,8-dien-1-ol | 1108 | — | 0.7 | — |
20 | Α-Campholenal | 1127 | — | 0.7 | 0.3 |
21 | cis-p-Mentha-2,8-dien-1-ol | 1136 | — | — | 0.1 |
22 | Sabinol | 1142 | 0.2 | 0.2 | 0.2 |
23 | cis-Verbenol | 1147 | — | 0.3 | 0.6 |
24 | Lavandulol | 1165 | — | — | 0.2 |
25 | trans-2-Caren-4-ol | 1172 | — | 0.1 | 0.3 |
26 | Terpinen-4-ol | 1179 | — | — | 0.5 |
27 | Cryptone | 1190 | — | 0.6 | 1.0 |
28 | Verbenone | 1216 | — | 0.2 | — |
29 | trans-Carveol | 1219 | — | — | 0.1 |
30 | Butanoic acid, 2-methyl-, hexyl ester | 1230 | 0.6 | — | — |
31 | Cumin aldehyde | 1244 | — | — | 0.4 |
32 | Phellandral | 1281 | — | — | 0.2 |
33 | δ-Elemene | 1339 | — | — | 0.1 |
34 | α-Terpineol acetate | 1345 | 2.5 | — | — |
35 | Cyclosativene | 1374 | — | — | 0.1 |
36 | Α-Copaene | 1379 | — | — | 0.1 |
37 | Β-Maaliene | 1388 | — | — | 0.1 |
38 | Β-Cubebene | 1392 | — | 0.2 | 0.5 |
39 | β-(E)-Caryophyllene | 1427 | 0.4 | 1.2 | 1.7 |
40 | Β-Gurjunene | 1435 | — | 0.3 | 0.6 |
41 | cis-β-Farnesene | 1450 | — | — | 0.3 |
42 | Humulene | 1461 | — | 0.2 | 0.4 |
43 | Γ-Gurjunene | 1464 | — | 0.2 | 0.4 |
44 | Γ-Muurolene | 1480 | — | 0.2 | 0.6 |
45 | Germacrene D | 1490 | 6.1 | 24.0 | 21.6 |
46 | Α-Muurolene | 1503 | — | 0.3 | 0.5 |
47 | Γ-Cadinene | 1523 | — | 0.3 | 0.9 |
48 | Δ-Cadinene | 1526 | — | — | 0.2 |
49 | Spathulenol | 1588 | — | — | 0.9 |
50 | Caryophyllene oxide | 1597 | — | 0.1 | 0.7 |
51 | Cedr-8-en-13-ol | 1656 | — | — | 0.2 |
52 | Cadalene | 1680 | 1.0 | 0.1 | — |
53 | 6-Isopropenyl-4,8a-dimethyl-1,2,3,5,6,7,8,8a-octahydro-naphthalen-2-ol | 1694 | — | — | 2.2 |
54 | Hexahydrofarnesyl acetone | 1747 | — | — | 0.9 |
Total (%) | 99.0 | 98.6 | 95.9 | ||
Monoterpene hydrocarbons | 87.7 | 68.6 | 59.0 | ||
Oxygenated monoterpenes | 3.0 | 2.9 | 3.9 | ||
Sesquiterpene hydrocarbons | 7.5 | 27.0 | 28.0 | ||
Oxygenated sesquiterpene | — | 0.1 | 4.9 | ||
Nonterpene ester | 0.8 | — | — |
Notes: aretention index; bcomposition calculated based on the peak area % of each fraction.