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. 2017 Nov 3;56(48):15451–15455. doi: 10.1002/anie.201708668

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© 2017 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial‐NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.

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Scheme 1 — Comparison with the previously reported in situ H₂O₂ generation method to promote peroxygenase‐catalyzed hydroxylations of alkanes using the recombinant peroxygenase from Agrocybe aegerita (rAaeUPO). Top: The previously reported multienzyme cascade comprising alcohol oxidase (AOx), formaldehyde dismutase (FDM), formate dehydrogenase (FDH), 3‐hydroxybenzoate‐6‐hydroxylase (3HB6H), as well as the nicotinamide cofactor (NADH/NAD⁺).3 Bottom: Photochemical oxidation of methanol using Au‐loaded TiO₂ (Au‐TiO₂).