Table 1.

Chemical shifts (ppm) of free Man₃ and CV-N-bound Man₃

		H1	H2	H3	H4	H5	H6a, H6b	OMe
		C1	C2	C3	C4	C5	C6
Man′	Free	5.02	4.04	3.81	3.61	3.73	3.72, 3.87
		104.9	72.8	73.2	69.6	76.0	63.9
	Bound	4.63	4.31	3.53	3.47	3.77	3.62, 3.89
		106.4	70.9	73.4	70.4	76.0	64.3
	Δδa	−0.39	0.27	−0.28	−0.14	0.05	−0.10, 0.02
		1.5	−1.9	0.2	0.8	0.0	0.4
Man″	Free	5.26	4.08	3.93	3.65	3.73	3.72, 3.87
		103.3	81.2	72.8	69.8	76.0	63.9
	Bound	5.45	3.77	4.22	3.55	3.95	3.66, 3.90
		103.5	83.6	73.7	71.6	74.4	64.5
	Δδa	0.19	−0.31	0.29	−0.11	0.23	−0.06, 0.03
		0.1	2.5	0.9	1.8	−1.6	0.6
Man	Free	4.95	3.91	3.84	3.64	3.57	3.75, 3.87	3.37
		102.0	81.4	73.0	69.9	75.3	63.8	57.6
	Bound	5.17	3.81	3.84	3.58	3.50	3.45, 3.70	3.42
		101.0	84.0	72.8	71.7	75.2	64.9	57.7
	Δδa	0.22	−0.09	0.01	−0.06	−0.07	−0.30, −0.17	0.05
		−1.0	2.6	−0.2	1.8	−0.1	1.2	0.1

^aΔδ = δ_bound − δ_free