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Thymidylate Synthase reactions. (A) The reaction catalyzed by classical Thymidylate Synthase (TSase; TS). (B) Reaction catalyzed by FDTS enzyme. R = 2′-deoxyribose-5′-phosphate; R′ = (p-aminobenzoyl)-glutamate; R″ = adenosine-5′-pyrophosphate-ribityl. Reprinted with permission from Ref. [7].
