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. Author manuscript; available in PMC: 2018 Oct 25.
Published in final edited form as: J Am Chem Soc. 2017 Oct 12;139(42):14857–14860. doi: 10.1021/jacs.7b08459

Table 2.

β-/γ- and δ-/ε-Desaturation of Alcoholsa

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a

Isolated yields; r.r. = regioisomeric ratio.

b

T1 was used.

c

T2 was used.

d

The desilylation step (TBAF) was omitted.

e

For 1v–1y, the trans precursor was used.

f

Contains minor amount of hydrodehalogenation byproduct.