a) The Raman spectra of the 2H phase (black) and the 1T′ phase (red) of MoTe2. The Raman spectra of from mono‐ to few‐layers of the TMDs in the 1T′ (or Td) phase. Reproduced with permission.105 Copyright 2015, American Association for the Advancement of Science. b) WTe2. Reproduced with permission.99 Copyright 2016, the authors, published under CC‐BY‐4.0 license. c) ReS2. Reproduced with permission.108 Copyright 2016, American Chemical Society. d) ReSe2. e) Scatter plot of the vibrational frequencies of the ReSe2 unit cell at the Γ point. d,e) Reproduced with permission.97 Copyright 2014, the authors, published under CC‐BY‐4.0 license. f) Optical absorption spectra of monolayer ReS2 and ReSe2 for the incident light polarized along the Γ‐K2 direction and the Γ‐M3 direction. g) Polarization‐dependent oscillator strength of excitons in monolayer ReS2, the exciton EΓ, the exciton EΛ and their combined oscillator strength in monolayer ReSe2 with a 50 meV smearing to mimic the absorption spectrum. Reproduced with permission.65 Copyright 2015, American Physical Society.