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. 2017 Dec 4;149(1):1–9. doi: 10.1007/s00706-017-2108-4

Fig. 8.

Fig. 8

Proposed mechanism of photosensitized T〈〉T dimerization in the triplet state. (i) Triplet–triplet energy transfer (TTET) from the photosensitizer (PS) to thymine–thymine, (ii) vibrational relaxation (VR) in T 1, (iii) 3BR formation by overcoming an energy barrier, (iv) intersystem crossing (iv), and (v) formation of thymine dimer or return to the Franck–Condon (FC) region in the electronic ground state