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. 2017 Dec 21;8:2245. doi: 10.1038/s41467-017-02148-1

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© The Author(s) 2017

Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

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Fig. 3 — Mechanistic studies. a Crystal structure of the key intermediate RhS–1f. b UV/Vis absorption spectra of RhS (0.05 mM), RhS–1f (0.05 mM), 1f (1.0 mM), and 2a (1.5 mM) in CH₂Cl₂. c Control experiment which rules out 2H-azirines as reaction intermediates. d Determination of quantum yield of 0.19. e Calculated spin distribution and energy of the excited triplet states of 1f, RhS–1f, and IrS–1f