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. Author manuscript; available in PMC: 2018 Sep 27.
Published in final edited form as: Chem Rev. 2017 Jun 5;117(18):11894–11951. doi: 10.1021/acs.chemrev.7b00022

Figure 23.

Figure 23

Site-selective glycosylation of digitoxin (87) in the presence of diphenylborinic acid catalyst 124, which proceeds via a cis-1,2-diol coordinating to the borinic acid.161