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. Author manuscript; available in PMC: 2018 Sep 27.
Published in final edited form as: Chem Rev. 2017 Jun 5;117(18):11894–11951. doi: 10.1021/acs.chemrev.7b00022

Figure 38.

Figure 38

(A) With a methyl ester, the innate substrate reactivity for C1–H atom abstraction followed by rearrangement and oxidation predominates. (B) The free carboxylate directs oxidation to C2–H.201